You visited us 1 times! Enjoying our articles? Unlock Full Access!

Byju's Answer

Standard X

Chemistry

Structural Isomerism

The necessary...

Question

The necessary and sufficient condition to exhibit optical activity, the configuration of the given complex should be assymmetric.
The complex which does not exhibit cis $-$ trans isomerism but optically active :

[Z n {(g l y)}_{3}]

Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses

[P t {(g l y)}_{2}]

No worries! We‘ve got your back. Try BYJU‘S free classes today!

{[N i {(g l y)}_{2}]}_{2}^{0}

No worries! We‘ve got your back. Try BYJU‘S free classes today!

[P d {(g l y)}_{2}]

No worries! We‘ve got your back. Try BYJU‘S free classes today!

Open in App

Solution

The correct option is C $[Z n {(g l y)}_{3}]$

Suggest Corrections

Similar questions

The following complexex are given:
(1) $t r a n s - [C o (N H_{3})_{4} C l_{2}]^{+}$
(2) $c i s - [C o (N H_{3})_{2} (e n)_{2}]^{3 +}$
(3) $t r a n s - [C o (N H_{3})_{2} (e n)_{2}]^{3 +}$
(4) $[N i C l_{4}]^{2 -}$
(5) $[T i F_{6}]^{2 -}$
(6) $[C o F_{6}]^{3 -}$
Choose the correct code:

Q. Consider the following complexes.
(i)

[C r (E D T A)]^{-}

(ii)

[R u (e n)_{3}]^{2 +}

(iii)

[P t (g l y)_{2} C l_{2}]^{- 2}

(iv)

C i s - [C r (C l)_{2} (o x)_{2}]^{3 -}

(v) trans -

[P t (e n) (N H_{3})_{2} (p y)_{2}]^{4 +}

Then find out the value of expression

| p + q |^{2}

p = total number of optically active complexes

q = total number of optically inactive complexes

Identify the optically active compounds from the following
(a) $[C o (e n)_{3}]^{3 +}$
(b) $t r a n s - [C o (e n)_{2} C l_{2}]^{+}$
(c) $c i s - [C o (e n)_{2} C l_{2}]^{+}$
(d) $[C r (N H_{3})_{5} C l]$

Q. Assertion :Statement

-

1 : Complexes containing three bidentate groups such as

{[C r {(o x)}_{3}]}_{3}^{3 -}

and

{[C o {(e n)}_{3}]}_{3}^{3 +}

do not show optical activity. Reason: Statement

-

2 : Octahedral complex,

[C o {(N H_{3})}_{4} C l_{2}] C l

shows geometrical isomerism.

Q. Match each coordination compound in List-I with an appropriate of characteristics from List-II. (

e n = H_{2} H C H_{2} C H_{2} N H_{2}

; Atomic numbers: Ti = 22, Cr = 24; Co = 27; Pt = 78)

	List I		List II
A	$[C r {({N H}_{3})}_{4} {C l}_{2}] C l$	1	Paramagnetic and exhibits ionization isomerism
B	$[T i {(H_{2} O)}_{3} C l] {({N O}_{3})}_{2}$	2	Diamagnetic and exhibits cis-trans isomerism
C	$[P t (e n) (N H_{3}) C l] {N O}_{3}$	3	Paramagnetic and exhibits cis-trans isomerism
D	$[C o {({N H}_{3})}_{4} {({N O}_{3})}_{2}] {N O}_{3}$	4	Diamagnetic and exhibits ionization isomerism

Join BYJU'S Learning Program

The necessary and sufficient condition to exhibit optical activity, the configuration of the given complex should be assymmetric.The complex which does not exhibit cis − trans isomerism but optically active :

The correct option is C [Zn(gly)3]

The necessary and sufficient condition to exhibit optical activity, the configuration of the given complex should be assymmetric.
The complex which does not exhibit cis $-$ trans isomerism but optically active :

The correct option is C $[Z n {(g l y)}_{3}]$