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Question

The nitrogen containing compound produced in the reaction of HNO3 with P4O10 is :

A
can also be prepared by reaction of P4 and HNO3
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B
is diamagnetic
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C
contains one NN bond
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D
reacts with Na metal producing a brown gas
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Solution

The correct options are
B is diamagnetic
D reacts with Na metal producing a brown gas
4HNO3+P4O102N2O5+4HPO3
So, nitrogen containing compound is N2O5

(A) P4+20HNO34H3PO4+20NO2+4H2O
N2O5 can't be prepared by reaction of P4 & HNO3.

(B) N2O5 is diamagnetic.

(C) Structure of N2O5 is: (image)

(D) N2O5+NaNaNO3+NO2
Nitrogen dioxide (NO2) appears as a reddish brown gas.

Options B and D are correct.

516516_478184_ans.jpg

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