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Question

The number of bridging ligands and the number of bromine atoms present per molecule of the compound decaammine-μ-hydroxodichromium(III) bromide are respectively:

A
1,5
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B
2,6
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C
1,4
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D
1,3
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Solution

The correct option is A 1,5
The structure of the compound is [(NH3)5Cr(OH)Cr(NH3)5]Br5.

Here, the ligand hydroxo (OH) is behaving as bridging ligand.

There are overall 2 chromium atoms and oxidation state of each Cr atom is +3.

So, to balance the charge, there should be 5 bromine atoms.

Option A is correct.

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