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Question

The number of different substitution products possible when bromine and ethane are allowed to react is?

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Solution

Since halogenation of alkanes is mostly uncontrolled, you are likely to get a mixture of mono and polysubstituted products. These will be-

Monosubstituted: 1

Disubstituted: 2

Trisubstituted: 2

Tetrasubstituted: 2

Pentasubstituted: 1

Hexasubstituted: 1

Thus, you get a total of 9 structural isomers.



C2H6(g) +Br2(l) --> C2H5Br(l) +HBr(g).

C2H6(g) +Br2(l) --> C2H4Br(l) +2HBr(g).

C2H6(g) +2Br2(l) --> C2H2(l) +4HBr(g).

C2H6(g) +3Br2(l) --> C2H3Br3(l) +3HBr(g).

C2H6(g) +Br2(l) --> CHBr(l) +HBr(g)+ CH4

C2H6(g) +4Br2(l) --> C2H5Br(l) + HBr(g) + 3Br2

C2H6(g) +2Br2(l) + H2 --> C2H5Br(l) +3HBr(g).

2C2H6(g) +Br2(l) --> C2H5Br(l) + HBr(g) + C2H6

C2H6(g) +3Br2(l) --> C2HBr(l) +5HBr(g).


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