The number of moles of KMnO4 that will be needed to react with one mole of sulphite ion in acidic solution is:
The balanced chemical reaction is :
2MnO−4+5CO2−4+16H+→2Mn2++5SO2−4+3H2O.
From the balanced chemical equation we can say that:
∵ 5 moles SO2−4 reacts with 2 moles of KMnO4.
∴ 1 mole SO2−4 reacts with 2/5 mole of KMnO4.
Hence, the correct option is A