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Question

The number of oxygen molecules in a cylinder of volume 1m3 at a temperature of 27oC and pressure 13.8Pa is:(Boltzmaans constant k=1.38×1023JK1:

A
6.23×1026
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B
0.33×1028
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C
3.3×1021
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D
None of these
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Solution

The correct option is C 3.3×1021

Given,

Pressure, P=13.8Pa

Temperature, T=(27+273.15)K

Volume V=1 m3

Boltzman constant kB=1.38×1023JK1

Runiversal=NAKB=(6.023×1023)×(1.38×1023)=8.314 J/mol

Apply Ideal gas equation

PV=nRT

n=PVRT=13.8×18.314(27+273.15)=5.53×103 mol

x=n×NA=(5.53×103)×(6.023×10+23)=3.33×1021 molecules

Number of molecules is 3.33×1021


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