There will be 4 possible outcomes if we throw two coins together in the form (p, q), where p is the outcome from the first coin and q is the outcome from the second coin.
(H, T), (H, H), (T, H), (T, T)
But all these outcomes are possible with 6 different outcomes of a die.
(H, T), (H, H), (T, H), (T, T) → 1
(H, T), (H, H), (T, H), (T, T) → 2
(H, T), (H, H), (T, H), (T, T) → 3
(H, T), (H, H), (T, H), (T, T) → 4
(H, T), (H, H), (T, H), (T, T) → 5
(H, T), (H, H), (T, H), (T, T) → 6
So, the total possible outcomes are 24.