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Question

The number of structural and configurational isomers of a bromo compound, C5H9Br, formed by the addition of one mole HBr to 2-pentyne respectively are

A
1 and 2
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B
2 and 4
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C
4 and 2
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D
2 and 1
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Solution

The correct option is B 2 and 4
Addition of HBr of 2-pentyne gives two structural isomers.
CH3CCCH2CH3HBr−−CH3C(Br)=CHCH2CH3+CH3CH=C(Br)CH2CH3
Each one of these will exist as a pair of geometrical isomers. Thus, there are two structural and four configurational isomers.
Hence, the correct answer is option (b).

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