Acidic Character, Basic Character and Nature of Oxides
The number of...
Question
The number of unpaired electrons in gaseous species of Mn3+, Cr3+, and V3+ are ____________ respectively and the most stable species is ______.
A
4, 3 and 2;V3+
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B
3, 3and 2;Cr3+
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C
4, 3 and 2 ; Cr3+
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D
3, 3 and 3; Mn3+
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Solution
The correct option is C 4, 3 and 2 ; Cr3+ The no. of unpaired e− s in the species are:
V3+ - [Ar]3d24s0 -2
Mn3+ - [Ar]3d44s0 -4
Cr3+- [Ar]3d34s0 -3
The most stable species is Cr3+ because Mn3+ will like to readily gain e− and charge itself into a more stable half filled configuration while V3+ likes to remove two e−s and gain inert gas stable configuration.