In CuSO4.5H2Othe metal ion is six coordinated. The coordination groups around the cupric ion are composed of 4 H2O and two oxygen atoms of sulphate ions and the fifth H2O is held between water molecules attached to cations and oxygen atoms of sulphate ions. The structure is given above.
The number of water molecule(s) directly bonded to the metal centre in CuSO4.5H2O is 4.