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Question

The numerical value of b is x times the actual volume occupied by one mole of gas molecule, then x is

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Solution

The numerical value of b is x times the actual volume occupied by one mole of gas molecule, then x is 4.
The effective volume, also called co-volume or excluded volume, of the molecules in motion has been calculated to be four times the actual volume of the molecules at rest.
b=4Vm

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