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Question

The numerical value of d/D when α=0 for PCl5PCl3+Cl2; where d are vapour density of equilibrium mixture and D is vapour density of PCl5.

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Solution

When the degree of dissociation α for PCl5PCl3+Cl2 is zero, the equilibrium mixture only consists of PCl5.
The vapor density of the equilibrium mixture will be equal to the vapor density of PCl5.
Hence, d=D and dD=1

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