The octahedral complex $C o S O_{4} C l_{5} N H_{3}$ exists in two isomeric forms $X$ and $Y$ . Isomers $X$ reacts with $A g N O_{3}$ to give a white precipitate, but does not react with $B a C l_{2}$ . Isomer $Y$ gives white precipitate with $B a C l_{2}$ but does not react with $A g N O_{3}$ .
Isomers $X$ and $Y$ are:

ionization isomers

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linkage isomers

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coordinating isomers

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solvent isomers

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Solution

The correct option is A ionization isomers
$[C o (N H_{3})_{5} S O_{4}] C l (X) A g N O_{3} - --- \to A g C l white ppt. ↓$

$[C o (N H_{3})_{5} C l] S O_{4} (Y) B a C l_{2} - -- \to B a S O_{4} white ppt. ↓$

$[X]$ and $[Y]$ are ionization isomers.

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Similar questions

Q. The octahedral complex

C o S O_{4} C l .5 N H_{3}

exists in two isomeric forms X and Y. Isomer X reacts with

A g N O_{3}

to give a white precipitate, but does not react with

B a C l_{2}

. Isomer Y gives white precipitate with

B a C l_{2}

but does not react with

A g N O_{3}

. Isomer X and Y are

$C o S O_{4} C l .5 N H_{3}$ exists in two isomeric forms 'A and 'B'. Isomer 'A' reacts with $A g N O_{3}$ to give white precipitate, but does not react with $B a C l_{2} .$ Isomer 'B' gives white precipitate with $B a C l_{2}$ but does not react with $A g N O_{3} .$ Answer the following questions.
(a) Identify \A' and 'B' and white their structural formulae
(b) Name the type of isomerism involved.
(c) Give the IUPAC name of 'A' and 'B'.