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Question

The % of αanomer in the mixture is:

A
32.6
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B
67.4
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C
42.6
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D
57.4
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Solution

The correct option is A 67.4
Specific rotation, [α]Tλ=α(g/ml)×l(dm)

Let, the % of α form is x.

Let, the % of β form is 100x.

Therefore, at equilibrium, 29×x+(100x)×(17)100=14

On solving, we get x=67.4

Therefore, % of α anomer in the mixture is 67.4%

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