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Question

The only element of group 13 which does not form a passive layer on the surface while dissolving in con. HNO3, but dissolve to form complex is:

A
boron
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B
aluminium
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C
both
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D
none
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Solution

The correct option is A boron
Boron does not usually react with acids and alkalis but it reacts with acids and alkalis in only highly divided state. When it reacts with HNO3 it gives Boric acid. The reaction occurs at high temperature.
B+3HNO3H3BO3+3NO2 which is complex in nature.

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