The correct option is A 4s
Aufbau principle states that an electron occupies orbitals in order from lowest energy to highest. Electrons are filled in orbitals in order of n+l . For subshells with the same n+l value, electrons are filled first in the subshell with lower value of n.
Orbitaln+l value3p44s43d64p64d7
Therefore, 4s will be filled after 3p as the value of n for 4s orbital is greater than 3p.