The order of acidic strength of boron trihalides is:
A
BF3<BCl3<BBr3<BI3
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B
BI3<BBr3<BCl3<BF3
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C
BCl3<BBr3<BI3<BF3
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D
BBr3<BCl3<BF3<BI3
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Solution
The correct option is BBF3<BCl3<BBr3<BI3 Boron trihalides are Lewis acid. The order of their acidic strength is as BF3<BCl3<BBr3<BI3. Less acidic nature of BF3 is due to π− back bonding.