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Question

The order of acidic strength of boron trihalides is:

A
BF3<BCl3<BBr3<BI3
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B
BI3<BBr3<BCl3<BF3
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C
BCl3<BBr3<BI3<BF3
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D
BBr3<BCl3<BF3<BI3
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Solution

The correct option is B BF3<BCl3<BBr3<BI3
Boron trihalides are Lewis acid. The order of their acidic strength is as BF3<BCl3<BBr3<BI3. Less acidic nature of BF3 is due to π back bonding.

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