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Question

The order of reactivity of carbonyl compounds for nucleophilic addition is:

A
H2C=O>RCHO>ArCHO>R2C=O>Ar2C=O
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B
ArCHO>Ar2C=O>RCHO>R2C=O>CH2C=O
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C
Ar2C=O>R2C=O>ArCHO>RCHO>H2C=O
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D
H2C=O>R2C=O>Ar2C=O>RCHO>ArCHO
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Solution

The correct option is A H2C=O>RCHO>ArCHO>R2C=O>Ar2C=O
For more reactivity for nucleophilic addition, the carbonyl carbon should be more electron deficient. Presence of R or Ar groups decrease this electron deficiency. More these groups present, less is the reactivity.

Hence, the required order is:
H2C=O>RCHO>ArCHO>R2C=0>Ar2C=0

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