The order of reactivity of carbonyl compounds for nucleophilic addition is:
A
H2C=O>RCHO>ArCHO>R2C=O>Ar2C=O
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B
ArCHO>Ar2C=O>RCHO>R2C=O>CH2C=O
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C
Ar2C=O>R2C=O>ArCHO>RCHO>H2C=O
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D
H2C=O>R2C=O>Ar2C=O>RCHO>ArCHO
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Solution
The correct option is AH2C=O>RCHO>ArCHO>R2C=O>Ar2C=O For more reactivity for nucleophilic addition, the carbonyl carbon should be more electron deficient. Presence of −R− or −Ar groups decrease this electron deficiency. More these groups present, less is the reactivity.