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Question

The order of reactivity of following alcohols with halogen acids is:

I. CH3CH2CH2OH

II. CH3CH2−C|HOH−CH3

III. CH3CH2−CH3|C|CH3−OH

A
II > I > III
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B
I > III > II
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C
III > II > I
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D
I > II > III
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Solution

The correct option is B III > II > I
Reactivity of alcohols towards halogen acids decreases in the order:
3o>2o>1o i.e., III>II>I

Since the tertiary carbocation formed is most stable than primary and secondary carbocation.

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