The order of reactivity of phenylmagnesium bromide (PhMgBr) with the following compounds.
A
III>II>I
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B
II>I>III
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C
I>III>II
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D
I>II>III
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Solution
The correct option is DI>II>III Since alkyl group has +I effect, Hence greater the number of alkyl attached to the carbonyl group, its reactivity towards nucleophilic addition reaction decreases. Secondly, as the steric crowding on carbonyl group increases, the reactivity decreases accordingly.
∴ Correct reactivity order for reaction with PhMgBr is: