The organic compound obtained during the addition of HBr to propene in the presence of peroxide catalyst is:
A
2-bromopropane
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B
2-bromopopene
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C
1-bromopropane
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D
1-bromopropene
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Solution
The correct option is C1-bromopropane The organic compound obtained during the addition of HBr to propene in the presence of peroxide catalyst is 1-bromopropane.
CH3−CH=CH2+HBr→CH3−CH2−CH2−Br
Bromine is added to less substituted terminal C atom. This effect is called peroxide effect or Kharasch effect or also popularly named as anti-Markownikoff's rule.