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Question

The organic compound obtained during the addition of HBr to propene in the presence of peroxide catalyst is:

A
2-bromopropane
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B
2-bromopopene
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C
1-bromopropane
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D
1-bromopropene
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Solution

The correct option is C 1-bromopropane
The organic compound obtained during the addition of HBr to propene in the presence of peroxide catalyst is 1-bromopropane.

CH3CH=CH2+HBrCH3CH2CH2Br

Bromine is added to less substituted terminal C atom. This effect is called peroxide effect or Kharasch effect or also popularly named as anti-Markownikoff's rule.

Option C is correct.

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