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Question

The osmotic pressure of decimolar solution of urea at 27oC is:

A
2.49 bar
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B
5.0 bar
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C
3.4 bar
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D
1.25 bar
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Solution

The correct option is A 2.49 bar
Given,
c=0.1 M
T=300 K
V=1 L
R=0.0821 L atm mol1 K1

Using the relation, π=cVRT

π=0.11×0.0821×300

π=2.463 atm=2.463×1.01325=2.49 bar

Hence A is the correct answer

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