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Question

The oxidation number of Cr in CrO5 is:

A
+10
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B
+8
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C
+6
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D
+4
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Solution

The correct option is C +6
In CrO5, one oxygen is attached to Cr through the double bond. It has oxidation number 2. Four oxygen atoms are attached to Cr atom through a single bond. Each of these oxygen has an oxidation number 1.

Let x be the oxidation number of chromium. The sum of all the oxidation numbers is zero.

Hence, x2+4(1)=0 and x=6.

Thus, the oxidation number of chromium in CrO5 is +6.

The structure of CrO5 is shown above.

106309_17935_ans.jpg

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