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Question

The oxidation number of iodine in each of the following compounds, IF7,IF5,KI,I2,ICI and HIO4 respectively, is :

A
+7,+5,1,0,+1,+7
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B
+7,+5,1,0,+2,+7
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C
+7,+5,1,0,+4,+7
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D
none of these
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Solution

The correct option is A +7,+5,1,0,+1,+7
Let x be the oxidation number of iodine.
Since, the overall charge on the complex is 0, the sum of oxidation states of all elements in it should be equal to 0.
IF7; x+7(1)=0;x=+7
IF5; x+5(1)=0;x=+5
KI; 1+x=0;x=1
I2; 2x=0;x=0
ICI; x1=0;x=+1
HIO4; 1+x+4(2)=0;x=+7
The oxidation number of iodine in IF7, IF5, KI,I2, ICI and HIO4 is +7, +5, 1, 0, +1 and +7 respectively.

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