The Oxidation potential of hydrogen electrode at PH=10 and PH2 at 1atm is :
0.51 V
0.00V
+0.59 V
0.059 V
Eox=E0ox−0.0591n log[H+]PH2 =0−0.05911 log[10−10]1=0.59v
The standard oxidation potential of Ni/Ni2+ electrode is 0.236 V. If this is combined with a hydrogen electrode in acid solution, at what pH of the solution will the measured emf be zero at 250C? assume [Ni2+]=1M and PH2=1atm