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Question

The P-T graph as given below was observe for a process on an ideal gas, which of the following statement is true?
879900_624055fc40274ed38e994e746e3495d7.png

A
w = +ve, ΔH = +ve
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B
w = -ve, ΔH = -ve
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C
w = -ve, ΔH = +ve
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D
w = +ve, ΔH = -ve
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Solution

The correct option is D w = -ve, ΔH = +ve
ΔH=nCpΔT

If temperature changes are positive then enthalpy change will be positive.

In this graph temperature changes is positive then enthalpy change is positive.

We know, VT

If the temperature is increased then the volume of gas will be increased.

W=P(V2V1)

As volume increases so (V2V1) is positive

so work done is negative.

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