The packing efficiency of the two- dimensional square unit cell shown below is :
Area od square of side length l=l2
Number of atoms in unit cell =1+4×14=2
Let, radius of each circle be r
Area occupied =πr2×2
Now, diagonal of square =l√2
⇒4r=l√2
r=l2√2
Now, Packing efficiency =Area occupiedTotalarea×100%
=2πr2l2×100%
=2πl2(2√2)2×l2×100%
=100×2π8%
⇒PackingEfficiency=78.54%