The pair having the same magnetic moment is:
[At. No ∴ Cr =24, Mn =25, Fe =26, Co =27]
Identical the number of unpaired electrons higher the magnetic moment
Metal ion Unpaired electrons
[Cr(H2O)6]2+Cr2+ 4
[Fe(H2O)6]2+Fe2+ 4
∴[Cr(H2O)6]2+and[Fe(H2O)6]2+ have identical magnetic moment.