The pair of compounds having metals in their highest oxidation state is
MnO2, FeCl3
MnO-4, Cro2Cl2
[Fe(CN)6]3-, [CO(CN)3]
[NiCl4]2-, [COCl4]-
In MnO-4, Mn+7 is in highest oxidation state possible for Mn.
In CrO2Cl2, Cr+6 is in highest oxidation state possible for Cr.