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Question

The percentage composition of Mohr's salt is as follows. Fe²+=14.32% NH4=9.20% SO4²‐=49% REST being water of crystallization.Find the empirical formula of Mohr's salt.

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Solution

Elements
Percentage
Atomic mass
Relative mass of atoms
Simplest ratio
Fe 14.32% 56 14.3256=0.25 0.250.25=1
NH4 9.20% 18 9.2018=0.50 0.50.25=2
H2O 27.57% 18 27.5718=1.5 1.50.25=6
SO4 49% 96 4996=0.5 0.50.25=2
Empirical formula = Fe(NH4)2(H2O)6SO2


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