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Question

The peroxide effect involves :

A
ionic mechanism
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B
free radical mechanism
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C
heterolytic fission of double bond
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D
homolytic fission of double bond
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Solution

The correct option is D free radical mechanism

Addition reaction of HBr to alkene in presence of peroxide follows free radical mechanism.

Here, bromine radical forms, which reacts with alkene and form anti-markovnikov's product.

Option B is product.

124190_22022_ans_763300e748f241288c275e008b20f1d3.PNG

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