The correct option is A Organo phosphate
Organophosphate (OP) compounds are the most widely used group of insecticides in the world. Their acute toxicity causes a hazard both to professional and amateur users. OPs were first recognised in 1854, but their general toxicity was not established until the 1930s. Tetraethyl pyrophosphate (TEPP) was the first OP insecticide, which was developed in Germany during World War Two as a by-product of nerve gas development. OPs are all derived from phosphoric acid. They are generally among the most acutely toxic of all pesticides to vertebrate animals. They are also unstable and therefore break down relatively quickly in the environment. So, organo phosphates are more toxic to vertebrates compared to organo chlorine, carbamates and parathion. Thus, option A is correct and other options are wrong.