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Byju's Answer
Standard XII
Chemistry
Nernst Equation
The pH in LHE...
Question
The pH in LHE of the following cell is, if
E
c
e
l
l
=
0.2364
V
.
P
t
,
(
H
2
)
(
1
a
t
m
)
|
H
⊕
(
x
M
)
|
|
H
⊕
(
1
M
)
(
1
a
t
m
)
|
P
t
,
(
H
2
)
Open in App
Solution
Anode :
H
2
(
1
a
t
m
)
→
2
H
⊕
(
x
M
)
+
2
e
−
Cathode :
2
H
⊕
(
1
M
)
+
2
e
−
→
H
2
,
(
1
a
t
m
)
0.2364
=
0
−
0.059
2
l
o
g
(
x
1
)
2
⇒
0.2364
0.059
=
−
l
o
g
x
=
p
H
⇒
pH = 4
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Q.
The hydrolysis constant of aniline hydrochloride in
M
/
32
solution of salt at 298 K from the following cell data at 298 K is:
P
t
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t
m
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|
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+
(
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M
/
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C
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N
H
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l
|
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t
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)
|
P
t
;
E
c
e
l
l
=
−
0.188
V
h
=
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×
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2
,
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Q.
The EMF of the cell
p
t
,
H
2
(
1
a
t
m
)
|
H
⊕
(
c
)
|
|
K
C
l
(
s
a
t
u
r
a
t
e
d
)
|
H
g
2
C
l
2
|
H
g
(
s
)
is
0.36
V. The RHE is know as calomel electrode and its standard electrode potential is +
0.242
V. Find the
H
⊕
ions concentration in LHE and hence find the pH of LHE.
Q.
P
t
(
H
2
)
|
H
+
(
p
H
=
2
)
|
H
+
(
p
H
=
3
)
|
P
t
(
H
2
)
1 atm 1 atm
The cell reaction for the given cell is:
Q.
In the following electrochemical cell,
P
t
|
H
2
(
x
a
t
m
)
|
H
⊕
(
p
H
=
y
)
|
|
Z
n
2
+
(
z
M
)
|
Z
n
E
⊖
c
e
l
l
=
E
c
e
l
l
. This will be possible when:
Q.
I
2
(
S
)
|
I
(
0.1
M
)
half cell is connected to
H
+
(
a
q
)
|
H
2
(
1
a
t
m
)
|
P
t
half cell and its half cell potential is found to be 0.7714 V. If
E
o
I
2
/
I
=
0.535
V
, the pH of
H
+
/
H
2
half cell will be:
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