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Question

The pH of a 10 ml aqueous solution of HCI is 4. The amount of water to be added to this solution in order to change its pH from 4 to 5 is

A
30 ml
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B
60 ml
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C
90 ml
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D
120 ml
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Solution

The correct option is B 90 ml
On diIution, mili equivalent of the solute remains constant.
Initially pH of HCI = 4
so normality of HCI =104 N
after dilution pH of HCl = 5
so normalityof HCI will be = 105 N
N1V1=N2V2
104×10=105×V
V=100mL
So, 90 mL of water should be added for this pH change.

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