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Question

The pH of a buffer is 6.745 . When 0.01 mole of NaOH is added to 1litre of it, the pH changes to 6.832 Its buffer capacity is:

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Solution

Buffer capacity is the no. of moles of acid or base to be added to 1L buffer solution to change its pH by 1 unit.
Buffer Capacity=no.ofmolesofOH/H+added(pHchange)(Volumeofsolution)
=0.01(6.8326.745)×1=0.010.087=0.1209

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