The pH of a buffer solution containing 2.0 mol per litre CH3COONa and 1.5 mol per litre CH3COOH is: (Ka for acetic acid is 1.8×10−5)
A
4.87
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B
5.8
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C
2.4
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D
9.2
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Solution
The correct option is A 4.87 The given solution is acidic buffer so Henderson-Hasselbach equation is pH=−logKa+log[Salt][Acid] pH=−log[1.8×10−4]+log[Salt][Acid] pH=−log[1.8×10−4]+log2.01.5 pH=4.745+0.124=4.869