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Question

The pH of a solution of H2O2 is 6.0. Some chloride gas is bubbled into this solution. Which of the following is correct ?

A
The pH of the resultant solution is less than 6.0 and oxygen gas is librated
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B
The pH of the resultant solution is less than 8.0
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C
ClO2 will be formed in the resultant solution
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D
None of these
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Solution

The correct option is B The pH of the resultant solution is less than 6.0 and oxygen gas is librated
The reaction is as follows:
H2O2 +Cl2 2HCl+O2

When H2O2 reacts with chlorine gas, it forms more acidic HCl and thus lowers the pH.

Hence,option A is correct.

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