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Question

The possible number of steroisomers of the product of following reaction reagent would be :
PhCH=CHCH(CH3)CHONH2OH−−−−

A
2
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B
4
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C
6
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D
8
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Solution

The correct option is D 8
Aldehydes reacts with hydroxyl amine to form oxime.
PhCH=CHCH(CH3)CHO+NH2OHPhCH=CHCH(CH3)CH=NOH+H2O
The product PhCH=CHCH(CH3)CH=NOH contains only one chiral carbon atom. Hence, it has 2n=21=2 optical isomers.
In addition it contains two double bonds. Hence it also has geometrical isomers. Each double bond will give cis-trans isomers. Thus, total number of possible stereoisomers are 8.

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