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Question

The presence of an OH group in an organic compound can be tested by:

A
adding sodium metal to it
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B
adding acetic acid with H2SO4 to it which will form ester
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C
both A and B
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D
none of the above
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Solution

The correct option is A adding acetic acid with H2SO4 to it which will form ester
Alcohols are weaker acid than water and they react with strong reactive metals like sodium to form alkoxidesRONa+
To form an ester from alcohol and carboxylic acid the reaction is Fischer esterification refluxed with a catalyst of conc.sulfuric acid.
ROH+RCOOHRCOOR+H2O

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