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Fluorides of Xenon

The presence ...

Question

The presence of peroxide, learning to anti-Markovnikov addition on unsymmetrical alkene involves

A

free radical mechanism

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B

homolytic fission of double bond

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C

ionic mechanism

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D

heterolytic fission of double bond

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Solution

The correct option is A
free radical mechanism

A free radical R-O is formed by the homolytic cleavage of R-O-O-R single bond.

$R - 0 - 0 - R \to 2 R - 0^{\cdot}$

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Q. Assertion :Heterolytic fission occurs readily in polar covalent bonds. Reason: Heterolytic fission involves breaking of bond in such a way that shared pair of electrons go with one atom.

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