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Question

The process of purification of metals is represented by the following scheme

Ti+2l2250CTil41400Tipure+I2


A
cupellation
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B
poling
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C
electrolytic refining
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D
van-Arkel method
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Solution

The correct option is D van-Arkel method
van Arkel method is used for the refining of zirconium or titanium.
For example crude zirconium is converted to volatile zirconium tetraiodide and then decomposed on a thungsten filament to pure metal
Zr+2I2ZrI4

ZrI4Zr+2I2

The scheme for the purification of Ti is as given below.

Ti+2I2250CTiI41400−−Tipure+I2

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