The products of the reaction between $C_{6} H_{5} {N H}_{2}, {C H C l}_{3}$ and $K O H$ are:

C_{6} H_{5} C l + {N H}_{4} C l + K C l

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C_{6} H_{5} C N + K C l + H_{2} O

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C_{6} H_{5} N C + K C l + H_{2} O

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C_{6} H_{5} O H + {N H}_{4} C l + H_{2} O

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Solution

The correct option is C $C_{6} H_{5} N C + K C l + H_{2} O$
The products of the reaction between $C_{6} H_{5} {N H}_{2}, {C H C l}_{3}$ and $K O H$ are $C_{6} H_{5} N C + K C l + H_{2} O$ .

$C_{6} H_{5} {N H}_{2} + {C H C l}_{3} + 3 K O H Δ - \to C_{6} H_{5} N C + 3 K C l + 3 H_{2} O$

It is an example of Hoffmann's carbylamine test/isocyanide test.

Aliphatic or aromatic primary amines on heating with chloroform and alcoholic $K O H$ give foul smelling alkyl isocyanides or carbylamines.

Secondary or tertiary amines do not give this test.

Option C is correct.

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Similar questions

C_{6} H_{5} N H_{2} + C H C l_{3} + K O H \to (A) \to (B) + H_{2} O

C_{6} H_{5} {N H}_{2}

C_{6} H_{5} {N H C H}_{3}

C_{6} H_{5} {C H}_{2} {N H}_{2}

C_{6} H_{5} {N H}_{2}

C_{6} H_{5} {N H C H}_{3}

C_{6} H_{5} {C H}_{2} {N H}_{2}

C_{6} H_{5} N_{2} C l C u C l / H C l - --------- \to C_{6} H_{5} C l + N_{2}

C_{6} H_{5} {N H}_{2}, C_{6} H_{5} N H M e, C_{6} H_{5} N M e_{2}, o - M e C_{6} H_{4} {N H}_{2}

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