The correct option is C 4→2
Given, work function for Sodium is 1.82 eV and K.E of fastest electron emitted is 0.73 eV.
Total energy incident on Sodium is 2.55 eV.
Energy levels of Hydrogen are of −13.6 eV,−3.4 eV,−1.51 eV,0.85 eV and so on.
Therefore, the photon corresponding to 2.55 eV is n=4 to n=2.