The radioactive decay 83Bi211⟶81Ti207, takes place in 100L closed vessel at 27oC. Starting with 2 moles of 83Bi211(t1/2=130sec), the pressure development in the vessel after 520sec will be:
A
1.875 atm
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B
0.2155 atm
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C
0.4618 atm
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D
4.618 atm
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Solution
The correct option is C0.4618 atm After 520 sec (4 half life) moles of product forms is 1.87 mole. So pressure developed is, P=1.87∗0.082∗300/100=0.46atm