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Byju's Answer
Standard XII
Chemistry
First Order Reaction
The rate cons...
Question
The rate constant and half life of a first order reaction are related to each other as:
A
t
1
2
=
0.693
K
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B
t
1
2
=
0.693
×
K
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C
K
=
0.693
×
t
1
2
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D
K
×
t
1
2
=
1
0.693
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Solution
The correct option is
A
t
1
2
=
0.693
K
t
1
2
=
0.693
K
Where,
t
1
2
is half life and
K
is rate constant.
Hence, the correct option is
A
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Similar questions
Q.
The rate of a first order reaction gets doubled when the temperature is doubled from
T
1
t
o
2
T
1
(in K).
E
a
is nearly constant activation energy at 1386 kcal. What is the value of
T
1
?
(given R=2
c
a
l
K
−
1
m
o
l
−
1
,ln2=0.693)
Q.
In a reversible reaction, study of the mechanism says that both the forward and reverse reaction follows first order kinetics. If the half - life of forward reaction,
⎛
⎜
⎝
t
1
2
⎞
⎟
⎠
f
is 400 sec and that of reverse reaction,
⎛
⎜
⎝
t
1
2
⎞
⎟
⎠
f
is 250 sec. The equilbrium constant
(
K
e
q
)
of the reaction is-
Given:
⎛
⎜
⎝
t
1
2
⎞
⎟
⎠
=
0.693
k
Q.
Which order reaction obeys the expression
t
1
/
2
=
1
k
.
a
in chemical kinetics?
(
a
= concentration of reactant,
k
= rate constant,
t
1
/
2
= half-life)
Q.
For a first order reaction,
A
→
P
,
t
1
/
2
(half-life) is
10
days. The time required for
1
t
h
4
conversion of A(in days) is: (ln
2
=
0.693
, ln
3
=
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).
Q.
If the half life period of a reaction is
0.693
k
, its order will be
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