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Question

The rate expression for the reaction A(g)+B(g)C(g) is kC2A C1/2B. What changes in the initial concentration of A and B will cause the rate of reaction increase by a factor of eight:

A
CA×2;CB×2
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B
CA×2;CB×4
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C
CA×1;CB×4
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D
CA×4;CB×1
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Solution

The correct option is B CA×2;CB×4
Given,
A(g)+B(g)C(g)

Rate expression =kC2A C1/2B
When concentration of A increases 2 times[2CA]When concentration of B increases 4 times[4CB]

New rate =k[2CA]2[4CB]1/2

=4×2k[CA]2[CB]1/2

New rate =8k[CA]2[CB]1/2

So, the new rate of reaction increased by factor eight.
In this case correct option is B.

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