The rate expression for the reaction A(g)+B(g)→C(g) iskC2AC1/2B. What changes in the initial concentration of A and B will cause the rate of reaction increase by a factor of eight:
A
CA×2;CB×2
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B
CA×2;CB×4
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C
CA×1;CB×4
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D
CA×4;CB×1
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Solution
The correct option is BCA×2;CB×4 Given, A(g)+B(g)→C(g)
Rate expression =kC2AC1/2B When concentration of Aincreases 2 times→[2CA]When concentration of Bincreases 4 times→[4CB]
New rate =k[2CA]2[4CB]1/2
=4×2k[CA]2[CB]1/2
New rate =8k[CA]2[CB]1/2
So, the new rate of reaction increased by factor eight.
In this case correct option is B.