The rate for a first order reaction is 0.639×10−2mol dm−1min−1 and the initial concentration is 0.2 mol dm−3. The half-life period is
Under the same reaction conditions, the initial concentration of 1.386 mol dm−3 of a substance becomes half in 40 s and 20 s through first order and zero order kinetics, respectively.
The ratio (k1/k0 of the rate constants for first order (k1) and zero order (k0)of the reaction is