The rate of a reaction doubles when its temperature changes from 300 K to 310 K. Activation energy of such a reaction will be: (R=8.314JK−1mol−1 and log102=0.301)
A
58.5kJmol−1
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B
60.5kJmol−1
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C
53.6kJmol−1
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D
48.6kJmol−1
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Solution
The correct option is C53.6kJmol−1 ∵r2r1=k2k1=2 Now 2.303log10k2k1=EaR[T2−T1T1T2] 2.303log102=Ea8.314×[310−300310×300] ∴Ea=2.303×0.301×8.314×310×30010=53598.6J =53.6kJmol−1