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Byju's Answer
Standard XII
Chemistry
Gibbs Free Energy & Spontaneity
The rate of d...
Question
The rate of disappearance of
A
in the reaction at equilibrium
A
⇌
B
is given by :
−
d
[
A
]
d
t
=
2
×
10
−
2
[
A
]
−
4
×
10
−
3
[
B
]
at
300
K
.
The equilibrium constant
K
c
is :
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Solution
The rate of disappearance of
A
in the reaction at equilibrium
A
⇌
B
is given by
−
d
[
A
]
d
t
=
k
f
[
A
]
−
k
b
[
B
]
=
2
×
10
−
2
[
A
]
−
4
×
10
−
3
[
B
]
at
300
K
.
The equilibrium constant,
K
c
=
K
f
K
b
=
2
×
10
−
2
4
×
10
−
3
=
5
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0
Similar questions
Q.
The rate of disappearance of
A
at two temperature for the equilibrium
A
⇌
B
is given by
−
d
[
A
]
d
t
=
2
×
10
−
2
[
A
]
−
4
×
10
−
3
[
B
]
at
300
K
−
d
[
A
]
d
t
=
4
×
106
−
2
[
A
]
−
16
×
10
−
4
[
B
]
at
400
K
Calculate:
(i) equilibrium constants at
300
K
and
400
K
and
(ii) heat of reaction.
Q.
The rate of disappearance of
A
at two temperature for the equilibrium
A
⇌
B
is given by :
−
d
[
A
]
d
t
=
2
×
10
−
2
[
A
]
−
4
×
10
−
3
[
B
]
at
300
K
−
d
[
A
]
d
t
=
4
×
10
−
2
[
A
]
−
16
×
10
−
4
[
B
]
at
400
K
Calculate :
(i) equilibrium constants at
300
K
and
400
K
and
(ii) heat of reaction.
Q.
The rate of disappearance of
A
at two temperature is given by:
A
⇌
B
I.
−
d
[
A
]
d
t
=
2
×
10
−
2
[
A
]
−
4
×
10
−
3
[
B
]
at
300
K
II.
−
d
[
A
]
d
t
=
4
×
10
−
2
[
A
]
−
16
×
10
−
4
[
B
]
at
400
K
The heat of reaction for the change is :
Q.
Rate of disappearance of the reactant
A
at two different temperature is given by
A
⇌
B
−
d
[
A
]
d
t
=
(
2
×
10
−
2
S
−
1
)
[
A
]
−
4
×
10
−
3
S
−
1
[
B
]
,
T
=
300
K
−
d
[
A
]
d
t
=
(
4
×
10
−
2
S
−
1
)
[
A
]
−
16
×
10
−
4
[
B
]
,
T
=
400
K
Calculate heat of reaction in the given temperature range, when equilibrium is set up.
Q.
The rate of disappearance of A at two temperatures is given by
A
⇌
B
i.
−
d
[
A
]
d
t
=
2
×
10
−
2
[
A
]
−
4
×
10
−
3
[
B
]
at 300 K
ii.
−
d
[
A
]
d
t
=
4
×
10
−
2
[
A
]
−
16
×
10
−
4
[
B
]
at 300 K
From the given values of heat of reaction which are incorrect
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